Intrinsically modified self-extinguishing fire-retardant epoxy resin using boron-polyol complex
نویسندگان
چکیده
Abstract A novel fire-retardant epoxy thermoset, containing boron polyol complex, was prepared and characterised. The additive a stoichiometric mixture of boric acid glycerol. Flame retardancy the resin improved by formation stable char layer that protected underlying from further burning. Phonon transport through polymer matrix via hydrogen bonding identified. acted as thermal bridge for intermolecular phonon to gain conductivity resulting early formation. between complex demonstrated using Fourier Transform Infrared Spectroscopy. high degree graphitization confirmed Raman Thermogravimetric analysis used decomposition confirm yield over 20%. Reaction fire test revealed enhancement in self-extinguishing properties blend compared neat epoxy. Cone calorimetry testing decreased peak heat release rate total smoke production effect compound matrix. Hydrogen bonding, thick at surface, blowing out caused pyrolytic gases escaping gaseous phase, were attributed retardancy. This research may find applications insulation material electronic circuit boards, coating aerospace materials, well building construction industries.
منابع مشابه
Flame Retardant Luffa Fiber Reinforced Composites with Epoxy Resin Matrices
In current years composites have concerned considerable importance as a potential operational material. Low cost, light weights, high specific modulus, renewability, and biodegradability are the most basic & common attractive features of composites that make them useful for industrial applications. Luffacylindrical locally called as “sponge-gourd” is one such natural resource whose potential as...
متن کاملPolyol from castor oil and epoxy resin for PU Coatings
Novel reactive polyols were synthesized via modification of castor oil, a renewable agricultural raw material with epoxy resin and triethylamine as a catalyst. This polyol was used for synthesis of polyurethane coating. Coating formulations were developed by reacting polyol with aromatic adduct, aliphatic adduct and castor oil based adduct in different NCO/OH ratio. All coating composition syst...
متن کاملMechanical and Thermal Properties of Chemically Modified Epoxy Resin
Diglycidyl ether of bisphenol-A (DGEBA), having number average molecular weight (Mn) 375, was modified by incorporating the hydroxyl terminated polybutadiene (HTPB) based prepolymer using isophorone diisocyanate as a coupling agent. To increase the compatibility between the epoxy resin and HTPB part, polar groups were introduced in the later to achieve physical and chemical interactions between...
متن کاملExperimental data on the properties of polymer-modified cement grouts using epoxy and acrylic resin emulsions
The use of additives to improve the quality of cement grouts is crucial for civil engineering, especially in foundation construction. This article presents experimental data concerning the compressive strength, elastic modulus, bleeding and injectability of microfine cement grouts modified with epoxy and acrylic resin emulsions. Strength properties were obtained at different curing ages. For fu...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Polymer Research
سال: 2023
ISSN: ['1572-8935', '1022-9760']
DOI: https://doi.org/10.1007/s10965-023-03641-6